Multi-electron reactivity of a cofacial di-tin(II) cryptand: partial reduction of sulfur and selenium and reversible generation of S3˙−

Multi-electron reactivity of a cofacial di-tin(II) cryptand: partial reduction of sulfur and selenium and reversible generation of S3˙−

Cofacial bimetallic tin( II ) ([Sn 2 ( m BDCA-5t)] 2-, 1) and lead( II ) ([Pb₂(mBDCA-5t)]²-, 2) complexes have been prepared by hexadeprotonation of hexacarboxamide cryptand m BDCA-5t-H₆ together with double Sn(II) or Pb(II) insertion. Reaction of 1 with elemental sulfur or selenium generates di-tin...

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Bibliographic Details
Main Authors: Dai, Yizhe (Author), Wu, Gang (Author), Cummins, Christopher C. (Author), Stauber, Julia M. (Contributor), Miller, Peter G (Contributor), Nocera, Daniel G. (Author)
Other Authors: Institute for Medical Engineering and Science (Contributor), Massachusetts Institute of Technology. Department of Biology (Contributor), Massachusetts Institute of Technology. Department of Chemical Engineering (Contributor), Massachusetts Institute of Technology. Department of Chemistry (Contributor), Nocera, Daniel G (Contributor)
Format: Article
Language:English
Published: Royal Society of Chemistry, 2018-07-30T18:08:10Z.
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