Signature of Metallic Behavior in the Metal-Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu)

Signature of Metallic Behavior in the Metal-Organic Frameworks M₃(hexaiminobenzene)₂ (M = Ni, Cu)

The two-dimensionally connected metal-organic frameworks (MOFs) Ni₃(HIB)₂ and Cu₃(HIB)₂ (HIB = hexaiminobenzene) are bulk electrical conductors and exhibit ultraviolet-photoelectron spectroscopy (UPS) signatures expected of metallic solids. Electronic band structure calculations confirm that in both...

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Main Authors: Gul, Sheraz (Author), Yano, Junko (Author), Stach, Eric A. (Author), Dou, Jinhu (Contributor), Sun, Lei (Contributor), Ge, Yicong (Contributor), Li, Wenbin (Contributor), Hendon, Christopher H (Contributor), Li, Ju (Contributor), Dinca, Mircea (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Massachusetts Institute of Technology. Department of Materials Science and Engineering (Contributor), Massachusetts Institute of Technology. Department of Nuclear Science and Engineering (Contributor), Massachusetts Institute of Technology. Research Laboratory of Electronics (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2018-10-05T15:31:26Z.
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