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|a Samundsett, Christian
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|a Massachusetts Institute of Technology. Department of Civil and Environmental Engineering
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|a Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science
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|a Massachusetts Institute of Technology. Department of Mechanical Engineering
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|a Nguyen, Hieu T.
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|a Jensen, Mallory Ann
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|a Buonassisi, Anthony
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|a MacDonald, Daniel G
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|a Sio, Hang C.
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|a Lai, Barry
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|a Li, Li
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|a Nguyen, Hieu T.
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|a Jensen, Mallory Ann
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|a Buonassisi, Anthony
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|a MacDonald, Daniel G
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|a Microscopic Distributions of Defect Luminescence From Subgrain Boundaries in Multicrystalline Silicon Wafers
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|b Institute of Electrical and Electronics Engineers (IEEE),
|c 2018-11-19T15:32:48Z.
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|z Get fulltext
|u http://hdl.handle.net/1721.1/119182
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|a We investigate the microscopic distributions of sub-band-gap luminescence emission (the so-called D-lines D1/D2/D3/D4) and the band-to-band luminescence intensity, near recombination-active subgrain boundaries in multicrystalline silicon wafers for solar cells. We find that the sub-band-gap luminescence from decorating defects/impurities (D1/D2) and from intrinsic dislocations (D3/D4) has distinctly different spatial distributions, and is asymmetric across the subgrain boundaries. The presence of D1/D2 is correlated with a strong reduction in the band-to-band luminescence, indicating a higher recombination activity. In contrast, D3/D4 emissions are not strongly correlated with the band-to-band intensity. Based on spatially resolved, synchrotron-based micro-X-ray fluorescence measurements of metal impurities, we confirm that high densities of metal impurities are present at locations with strong D1/D2 emission but low D3/D4 emission. Finally, we show that the observed asymmetry of the sub-band-gap luminescence across the subgrain boundaries is due to its inclination below the wafer surface. Based on the luminescence asymmetries, the subgrain boundaries are shown to share a common inclination locally, rather than being orientated randomly.
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|a Australian Research Council
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|a Australian Renewable Energy Agency (gramt RND009)
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|a National Science Foundation (U.S.). Graduate Research Fellowship (Grant No.1122374)
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|a United States. Department of Energy. Office of Science (Contract No. DE-AC02-06CH11357)
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|a Article
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|t IEEE Journal of Photovoltaics
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