A Synthetic Model of Enzymatic [Fe₄S₄]-Alkyl Intermediates

Although alkyl complexes of [Fe₄S₄] clusters have been invoked as intermediates in a number of enzymatic reactions, obtaining a detailed understanding of their reactivity patterns and electronic structures has been difficult owing to their transient nature. To address this challenge, we herein repor...

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Bibliographic Details
Main Authors: Ye, Mengshan (Author), Thompson, Niklas B. (Author), Brown, Alexandra C. (Author), Suess, Daniel L. M. (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2019-09-23T18:18:36Z.
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