Synthesis of Molybdenum(VI) Neopentylidene Neopentylidyne Complexes
Mo(C-t-Bu)(CH-t-Bu)(Cl)(PMe₂Ph)₂ (1) was prepared as off-white crystals in 26% yield through addition of 2.5 equiv of Mg(CH₂-t-Bu)₂ to Mo(O)[OC(CF₃)₃]₄ in diethyl ether followed by 3 equiv of PMe₂Ph and a workup that includes dichloromethane (the source of Cl). Compound 1 is largely a syn isomer ini...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society (ACS),
2019-09-25T20:35:22Z.
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| Subjects: | |
| Online Access: | Get fulltext |