Bench-stable N -heterocyclic carbene nickel precatalysts for C−C and C−N bond-forming reactions

Herein, we introduce a new class of bench-stable N-heterocyclic carbene (NHC) nickel-precatalysts for homogeneous nickel-catalysis. The nickel(II) complexes are readily activated to Ni0 in situ under mild conditions, via a proposed Heck-type mechanism. The precatalysts are shown to facilitate carbon...

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Bibliographic Details
Main Authors: Strieth-Kalthoff, Felix (Author), Longstreet, Ashley R. (Author), Weber, Jessica Marie (Author), Jamison, Timothy F (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: Wiley, 2020-06-23T19:07:24Z.
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