Bench-stable N -heterocyclic carbene nickel precatalysts for C−C and C−N bond-forming reactions

Bench-stable N -heterocyclic carbene nickel precatalysts for C−C and C−N bond-forming reactions

Herein, we introduce a new class of bench-stable N-heterocyclic carbene (NHC) nickel-precatalysts for homogeneous nickel-catalysis. The nickel(II) complexes are readily activated to Ni0 in situ under mild conditions, via a proposed Heck-type mechanism. The precatalysts are shown to facilitate carbon...

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Bibliographic Details
Main Authors: Strieth-Kalthoff, Felix (Author), Longstreet, Ashley R. (Author), Weber, Jessica Marie (Author), Jamison, Timothy F (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: Wiley, 2020-06-23T19:07:24Z.
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100 1 0 |a Strieth-Kalthoff, Felix  |e author 
100 1 0 |a Massachusetts Institute of Technology. Department of Chemistry  |e contributor 
700 1 0 |a Longstreet, Ashley R.  |e author 
700 1 0 |a Weber, Jessica Marie  |e author 
700 1 0 |a Jamison, Timothy F  |e author 
245 0 0 |a Bench-stable N -heterocyclic carbene nickel precatalysts for C−C and C−N bond-forming reactions 
260 |b Wiley,   |c 2020-06-23T19:07:24Z. 
856 |z Get fulltext  |u https://hdl.handle.net/1721.1/125950 
520 |a Herein, we introduce a new class of bench-stable N-heterocyclic carbene (NHC) nickel-precatalysts for homogeneous nickel-catalysis. The nickel(II) complexes are readily activated to Ni0 in situ under mild conditions, via a proposed Heck-type mechanism. The precatalysts are shown to facilitate carbonyl-ene, hydroalkenylation, and amination reactions. 
520 |a NIH Ruth L. Kirschstein National Research Service Award (no. F32GM120852) 
546 |a en 
655 7 |a Article 
773 |t 10.1002/CCTC.201800454 
773 |t ChemCatChem 

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