Quo vadis niobium? Divergent coordination behavior of early-transition metals towards MOF-5
Treatment of MOF-5 with NbCl[subscript 4](THF)[subscript 2] in acetonitrile leads to incorporation of Nb(iv) centers in a fashion that diverges from the established cation metathesis reactivity of this iconic material. A combination of X-ray absorption spectroscopy analysis and reactivity studies al...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Royal Society of Chemistry (RSC),
2020-07-17T19:05:24Z.
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| Subjects: | |
| Online Access: | Get fulltext |