Modeling the roles of rigidity and dopants in single-atom methane-to-methanol catalysts
Doped graphitic single-atom catalysts (SACs) with isolated iron sites have similarities to natural enzymes and molecular biomimetics that can convert methane to methanol via a radical rebound mechanism with high-valent Fe(IV)[double bond, length as m-dash]O intermediates. To understand the relations...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Royal Society of Chemistry (RSC),
2022-02-10T16:37:06Z.
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| Subjects: | |
| Online Access: | Get fulltext |