Frustrated Lewis Pair Stabilized Phosphoryl Nitride (NPO), a Monophosphorus Analogue of Nitrous Oxide (N2O)

Phosphoryl nitride (NPO) is a highly reactive intermediate, and its chemistry has only been explored under matrix isolation conditions so far. Here we report the synthesis of an anthracene (A) and phosphoryl azide based molecule (N3P(O)A) that acts as a molecular synthon of NPO. Experimentally, N3P(...

Full description

Bibliographic Details
Main Authors: Eckhardt, André K. (Author), Riu, Martin-Louis Y. (Author), Müller, Peter (Author), Cummins, Christopher C. (Author)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2022-04-14T19:00:03Z.
Subjects:
Online Access:Get fulltext