Divergent Adsorption Behavior Controlled by Primary Coordination Sphere Anions in the Metal-Organic Framework Ni<sub>2</sub>X<sub>2</sub>BTDD
CO, ethylene, and H2 demonstrate divergent adsorption enthalpies upon interaction with a series of anion-exchanged Ni2X2BTDD materials (X = OH, F, Cl, Br; H2BTDD = bis(1H-1,2,3-triazolo[4,5-b][4',5'-i])dibenzo[1,4]dioxin)). The dissimilar responses of these conventional π-acceptor gaseous...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society (ACS),
2022-04-14T19:01:48Z.
|
| Subjects: | |
| Online Access: | Get fulltext |