Divergent Adsorption Behavior Controlled by Primary Coordination Sphere Anions in the Metal-Organic Framework Ni<sub>2</sub>X<sub>2</sub>BTDD

Divergent Adsorption Behavior Controlled by Primary Coordination Sphere Anions in the Metal-Organic Framework Ni<sub>2</sub>X<sub>2</sub>BTDD

CO, ethylene, and H2 demonstrate divergent adsorption enthalpies upon interaction with a series of anion-exchanged Ni2X2BTDD materials (X = OH, F, Cl, Br; H2BTDD = bis(1H-1,2,3-triazolo[4,5-b][4',5'-i])dibenzo[1,4]dioxin)). The dissimilar responses of these conventional π-acceptor gaseous...

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Bibliographic Details
Main Authors:	Oppenheim, Julius J. (Author), Mancuso, Jenna L. (Author), Wright, Ashley M. (Author), Rieth, Adam J. (Author), Hendon, Christopher H. (Author), Dincǎ, Mircea (Author)
Format:	Article
Language:	English
Published:	American Chemical Society (ACS), 2022-04-14T19:01:48Z.
Subjects:	Article
Online Access:	Get fulltext

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