Simple Molybdenum(IV) Olefin Complexes of the Type Mo(NR)(X)(Y)(olefin)

Simple Molybdenum(IV) Olefin Complexes of the Type Mo(NR)(X)(Y)(olefin)

Exposure of heptane solutions of Mo(NAr)(CHCMe2Ph)(Me2Pyr)(OAr) (1a; Ar = 2,6-diisopropylphenyl), Mo(NAr)(CHCMe3)(Me2Pyr)[OCMe(CF3)2] (1b), and Mo(NAr)(CHCMe2Ph)(Me2Pyr)(OSiPh3) (1c) to one atmosphere of ethylene for 12 h yields the ethylene complexes, Mo(NAr)(CH2CH2)(Me2Pyr)(OAr) (2a), Mo(NAr)(CH2C...

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Main Authors: Marinescu, Smaranda C. (Contributor), King, Annie J. (Contributor), Schrock, Richard Royce (Contributor), Singh, Rojendra (Contributor), Muller, Peter (Contributor), Takase, Michael K. (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society, 2012-03-14T21:03:18Z.
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