High Field Dynamic Nuclear Polarization with High-Spin Transition Metal Ions

High Field Dynamic Nuclear Polarization with High-Spin Transition Metal Ions

We report the dynamic nuclear polarization of 1H spins in magic-angle-spinning spectra recorded at 5 T and 84 K via the solid effect using Mn2+ and Gd[superscript 3+] complexes as polarizing agents. We show that the magnitude of the enhancements can be directly related to the effective line width of...

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Main Authors: Barnes, Alexander (Contributor), Corzilius, Bjorn (Contributor), Griffin, Robert Guy (Contributor), Bertini, Ivano (Author), Luchinat, Claudio (Author), Smith, Albert A. (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) (Contributor), Smith, Albert Andrew (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2012-08-08T14:58:51Z.
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