High Field Dynamic Nuclear Polarization with High-Spin Transition Metal Ions
We report the dynamic nuclear polarization of 1H spins in magic-angle-spinning spectra recorded at 5 T and 84 K via the solid effect using Mn2+ and Gd[superscript 3+] complexes as polarizing agents. We show that the magnitude of the enhancements can be directly related to the effective line width of...
Main Authors: | Barnes, Alexander (Contributor), Corzilius, Bjorn (Contributor), Griffin, Robert Guy (Contributor), Bertini, Ivano (Author), Luchinat, Claudio (Author), Smith, Albert A. (Author) |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry (Contributor), Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) (Contributor), Smith, Albert Andrew (Contributor) |
Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2012-08-08T14:58:51Z.
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Subjects: | |
Online Access: | Get fulltext |
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