Reductive electrosynthesis of crystalline metal-organic frameworks
Electroreduction of oxoanions affords hydroxide equivalents that induce selective deposition of crystalline metal-organic frameworks (MOFs) on conductive surfaces. The method is illustrated by cathodic electrodeposition of Zn[subscript 4]O(BDC)[subscript 3] (MOF-5; BDC = 1,4-benzenedicarboxylate), w...
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Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2012-10-15T16:47:21Z.
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Subjects: | |
Online Access: | Get fulltext |