Claisen Rearrangement of Graphite Oxide: A Route to Covalently Functionalized Graphenes

Claisen Rearrangement of Graphite Oxide: A Route to Covalently Functionalized Graphenes

On the GO: The basal plane allylic alcohol functionality of graphite oxide (GO) can be converted into N,N-dimethylamide groups through an Eschenmoser-Claisen sigmatropic rearrangement by using N,N-dimethylacetamide dimethyl acetal. Subsequent saponification of these groups affords the carboxylic aci...

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Main Authors: Collins, William R. (Contributor), Lewandowski, Wiktor (Contributor), Schmois, Ezequiel (Contributor), Walish, Joseph John (Author), Swager, Timothy M (Author)
Other Authors: Massachusetts Institute of Technology. Institute for Soldier Nanotechnologies (Contributor), Massachusetts Institute of Technology. Department of Chemical Engineering (Contributor), Massachusetts Institute of Technology. Department of Chemistry (Contributor), Swager, Timothy M. (Contributor), Walish, Joseph (Contributor), Swager, Timothy Manning (Contributor)
Format: Article
Language:English
Published: Wiley Blackwell, 2012-10-24T16:30:11Z.
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