Lattice-Imposed Geometry in Metal-Organic Frameworks: Lacunary Zn4O Clusters in MOF-5 Serve as Tripodal Chelating Ligands for Ni2+
The inorganic clusters in metal-organic frameworks can be used to trap metal ions in coordination geometries that are difficult to achieve in molecular chemistry. We illustrate this concept by using the well-known basic carboxylate clusters in Zn[subscript 4]O(1,4-benzenedicarboxylate)3 (MOF-5) as t...
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| Format: | Article |
| Language: | English |
| Published: |
Royal Society of Chemistry, The,
2013-04-04T16:57:22Z.
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| Subjects: | |
| Online Access: | Get fulltext |