Application of a New Chiral Phosphepine to the Catalytic Asymmetric Synthesis of Highly Functionalized Cyclopentenes That Bear an Array of Heteroatom-Substituted Quaternary Stereocenters
Through the design and synthesis of a new chiral phosphepine, the first catalytic asymmetric method for the [3 + 2] cycloaddition of allenes with olefins has been developed that generates cyclopentenes that bear nitrogen-, phosphorus-, oxygen-, and sulfur-substituted quaternary stereocenters. A wide...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society,
2013-11-06T21:27:25Z.
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| Subjects: | |
| Online Access: | Get fulltext |