Dynamic Nuclear Polarization with a Water-Soluble Rigid Biradical

Dynamic Nuclear Polarization with a Water-Soluble Rigid Biradical

A new biradical polarizing agent, bTbtk-py, for dynamic nuclear polarization (DNP) experiments in aqueous media is reported. The synthesis is discussed in light of the requirements of the optimum, theoretical, biradical system. To date, the DNP NMR signal enhancement resulting from bTbtk-py is the l...

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Bibliographic Details
Main Authors: Kiesewetter, Matthew K. (Contributor), Smith, Albert A. (Contributor), Corzilius, Bjorn (Contributor), Griffin, Robert Guy (Contributor), Swager, Timothy M (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) (Contributor), Swager, Timothy Manning (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2013-11-12T13:26:05Z.
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