Modeling the Syn Disposition of Nitrogen Donors in Non-Heme Diiron Enzymes. Synthesis, Characterization, and Hydrogen Peroxide Reactivity of Diiron(III) Complexes with the Syn N-Donor Ligand H[subscript 2]BPG[subscript 2]DEV

Modeling the Syn Disposition of Nitrogen Donors in Non-Heme Diiron Enzymes. Synthesis, Characterization, and Hydrogen Peroxide Reactivity of Diiron(III) Complexes with the Syn N-Donor Ligand H[subscript 2]BPG[subscript 2]DEV

In order to model the syn disposition of histidine residues in carboxylate-bridged non-heme diiron enzymes, we prepared a new dinucleating ligand, H[subscript 2]BPG[subscript 2]DEV, that provides this geometric feature. The ligand incorporates biologically relevant carboxylate functionalities, which...

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Main Authors: Friedle, Simone (Contributor), Kodanko, Jeremy J. (Contributor), Morys, Anna J. (Contributor), Hayashi, Takahiro (Author), Lippard, Stephen J. (Contributor), Moenne-Loccoz, Pierre (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2013-11-15T19:38:30Z.
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