Highly Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions Catalyzed by Stereogenic-at-Mo Adamantylimido Complexes
The first highly Z- and enantioselective class of ring-opening/cross-metathesis reactions is presented. Transformations are promoted in the presence of <2 mol % of chiral stereogenic-at-Mo monoaryloxide complexes bearing an adamantylimido ligand that are prepared and used in situ. Reactions invol...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2013-11-22T14:46:10Z.
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Subjects: | |
Online Access: | Get fulltext |