Cis, Isotactic Selective ROMP of Norbornenes Fused with N-Arylpyrrolidines. Double Stranded Polynorbornene-Based Ladderphanes with Z-Double Bonds

Cis, Isotactic Selective ROMP of Norbornenes Fused with N-Arylpyrrolidines. Double Stranded Polynorbornene-Based Ladderphanes with Z-Double Bonds

Upon treatment with a molybdenum-carbene with bidentate substituted biaryl-o,o'-diphenoxide ligand 12, norbornene fused with N-aryl-endo-pyrrolidine 9a undergoes ROMP to give exclusively polynorbornene with cis, isotactic-selectivity. Bis(norbornenes) connected with ferrocene 18 or benzene 20 l...

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Main Authors: Zhu, Lei (Author), Flook, Margaret M. (Contributor), Lee, Shern-Long (Author), Chan, Li-Wei (Author), Huang, Shou-Ling (Author), Chiu, Ching-Wen (Author), Chen, Chun-Hsien (Author), Luh, Tien-Yau (Author), Schrock, Richard Royce (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2014-01-27T14:10:00Z.
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