Cis, Isotactic Selective ROMP of Norbornenes Fused with N-Arylpyrrolidines. Double Stranded Polynorbornene-Based Ladderphanes with Z-Double Bonds
Upon treatment with a molybdenum-carbene with bidentate substituted biaryl-o,o'-diphenoxide ligand 12, norbornene fused with N-aryl-endo-pyrrolidine 9a undergoes ROMP to give exclusively polynorbornene with cis, isotactic-selectivity. Bis(norbornenes) connected with ferrocene 18 or benzene 20 l...
Main Authors: | , , , , , , , , |
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Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2014-01-27T14:10:00Z.
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Subjects: | |
Online Access: | Get fulltext |