Cyclobutadiene-C[subscript 60] Adducts: N-Type Materials for Organic Photovoltaic Cells with High V[subscript OC]

New tetraalkylcyclobutadiene-C[subscript 60] adducts are developed via Diels-Alder cycloaddition of C[subscript 60] with in situ generated cyclobutadienes. The cofacial π-orbital interactions between the fullerene orbitals and the cyclobutene are shown to decrease the electron affinity and thereby i...

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Bibliographic Details
Main Authors: Han, Ggoch Ddeul (Contributor), Collins, William R. (Contributor), Andrew, Trisha Lionel (Contributor), Bulovic, Vladimir (Contributor), Swager, Timothy Manning (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Massachusetts Institute of Technology. Department of Electrical Engineering and Computer Science (Contributor), Massachusetts Institute of Technology. School of Engineering (Contributor), Swager, Timothy M. (Contributor)
Format: Article
Language:English
Published: Wiley Blackwell, 2014-01-27T19:28:11Z.
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