Reversible binding of nitric oxide to an Fe(iii) complex of a tetra-amido macrocycle
Nitric oxide binds reversibly to the Fe(III) complex of a well-developed tetra-amido macrocyclic ligand. Reaction with NO results in formation of a species consistent with an S = 1 {Fe-NO}[superscript 6] ground state as characterized by UV-vis, IR, EPR, and Mössbauer spectroscopy. The resultant nit...
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| Format: | Article |
| Language: | English |
| Published: |
Royal Society of Chemistry,
2014-01-31T16:54:04Z.
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| Subjects: | |
| Online Access: | Get fulltext |