Twofold C−H Functionalization: Palladium-Catalyzed Ortho Arylation of Anilides
The ortho arylation of anilides to form biphenyls via a twofold C−H functionalization/C−C bond-forming process is described. The oxidative coupling takes place in the presence of 5−10 mol % of Pd(OAc)[subscript 2], 10−20 mol % of DMSO, and 4−11 equiv of the aryl substrate in TFA under an oxygen atmo...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society,
2014-05-21T20:14:04Z.
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| Subjects: | |
| Online Access: | Get fulltext |