Z-Selective Ring-Opening Metathesis Polymerization of 3-Substituted Cyclooctenes by Monoaryloxide Pyrrolide Imido Alkylidene (MAP) Catalysts of Molybdenum and Tungsten

Ring-opening metathesis polymerization of a series of 3-substituted cyclooctenes (3-MeCOE, 3-HexCOE, and 3-PhCOE) initiated by various Mo and W MAP complexes leads to cis,HT-poly(3-RCOE) polymers. The apparent rate of polymerization of 3-HexCOE by W(N-t-Bu)(CH-t-Bu)(Pyr)(OHMT) (1c; Pyr = pyrrolide;...

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Bibliographic Details
Main Authors:	Jeong, Hyangsoo (Contributor), Kozera, Daniel J. (Contributor), Smith, Stacey J. (Contributor), Zhang, Jihua (Author), Ren, Ning (Author), Hillmyer, Marc A. (Author), Schrock, Richard Royce (Contributor)
Other Authors:	Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format:	Article
Language:	English
Published:	American Chemical Society (ACS), 2014-08-26T14:18:27Z.
Subjects:	Article
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Z-Selective Ring-Opening Metathesis Polymerization of 3-Substituted Cyclooctenes by Monoaryloxide Pyrrolide Imido Alkylidene (MAP) Catalysts of Molybdenum and Tungsten

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