Palladium-Catalyzed Completely Linear-Selective Negishi Cross-Coupling of Allylzinc Halides with Aryl and Vinyl Electrophiles

Completely linear: The title reaction provides an effective means to access a wide range of prenylated arenes and "skipped dienes" in a completely linear-selective fashion, as demonstrated by a concise synthesis of the anti-HIV natural product siamenol. DFT calculations shed light on the o...

Full description

Bibliographic Details
Main Authors: Yang, Yang (Contributor), Mustard, Thomas J. L. (Author), Cheong, Paul Ha-Yeon (Author), Buchwald, Stephen Leffler (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: Wiley Blackwell, 2015-02-12T20:27:04Z.
Subjects:
Online Access:Get fulltext