High-Field [superscript 13] C Dynamic Nuclear Polarization with a Radical Mixture

High-Field [superscript 13] C Dynamic Nuclear Polarization with a Radical Mixture

We report direct [superscript 13]C dynamic nuclear polarization at 5 T under magic-angle spinning (MAS) at 82 K using a mixture of monoradicals with narrow EPR linewidths. We show the importance of optimizing both EPR linewidth and electron relaxation times by studying direct DNP of [superscript 13]...

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Bibliographic Details
Main Authors: Michaelis, Vladimir K. (Contributor), Smith, Albert A. (Contributor), Haze, Olesya (Contributor), Corzilius, Bjorn (Contributor), Griffin, Robert Guy (Contributor), Swager, Timothy M (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) (Contributor), Swager, Timothy Manning (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2015-02-18T21:40:20Z.
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