Nickel-Catalyzed Mizoroki-Heck Reaction of Aryl Sulfonates and Chlorides with Electronically Unbiased Terminal Olefins: High Selectivity for Branched Products
Achieving high selectivity in the Heck reaction of electronically unbiased alkenes has been a longstanding challenge. Using a nickel-catalyzed cationic Heck reaction, we were able to achieve excellent selectivity for branched products (≥19:1 in all cases) over a wide range of aryl electrophiles and...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
Wiley-VCH Verlag GmbH & Co.,
2015-02-19T19:08:30Z.
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Subjects: | |
Online Access: | Get fulltext |