Nickel-Catalyzed Mizoroki-Heck Reaction of Aryl Sulfonates and Chlorides with Electronically Unbiased Terminal Olefins: High Selectivity for Branched Products

Achieving high selectivity in the Heck reaction of electronically unbiased alkenes has been a longstanding challenge. Using a nickel-catalyzed cationic Heck reaction, we were able to achieve excellent selectivity for branched products (≥19:1 in all cases) over a wide range of aryl electrophiles and...

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Bibliographic Details
Main Authors: Tasker, Sarah Z. (Author), Gutierrez, Alicia C. (Contributor), Jamison, Timothy F. (Contributor), Tasker, Sarah Zinnen (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: Wiley-VCH Verlag GmbH & Co., 2015-02-19T19:08:30Z.
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