Observation of the simplest Criegee intermediate CH[subscript 2]OO in the gas-phase ozonolysis of ethylene
Ozonolysis is one of the dominant oxidation pathways for tropospheric alkenes. Although numerous studies have confirmed a 1,3-cycloaddition mechanism that generates a Criegee intermediate (CI) with form R[subscript 1]R[subscript 2]COO, no small CIs have ever been directly observed in the ozonolysis...
Main Authors: | , , , , |
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Format: | Article |
Language: | English |
Published: |
American Association for the Advancement of Science (AAAS),
2015-04-07T19:14:43Z.
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Online Access: | Get fulltext |