Observation of the simplest Criegee intermediate CH[subscript 2]OO in the gas-phase ozonolysis of ethylene

Ozonolysis is one of the dominant oxidation pathways for tropospheric alkenes. Although numerous studies have confirmed a 1,3-cycloaddition mechanism that generates a Criegee intermediate (CI) with form R[subscript 1]R[subscript 2]COO, no small CIs have ever been directly observed in the ozonolysis...

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Bibliographic Details
Main Authors: Womack, Caroline C. (Contributor), Martin-Drumel (Author), Brown, Gordon G. (Author), Field, Robert W. (Contributor), McCarthy, Michael C. (Author)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: American Association for the Advancement of Science (AAAS), 2015-04-07T19:14:43Z.
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