Palladium-Catalyzed Hydroxylation of Aryl and Heteroaryl Halides Enabled by the Use of a Palladacycle Precatalyst
A method for the hydroxylation of aryl and heteroaryl halides, promoted by a catalyst based on a biarylphosphine ligand tBuBrettPhos (L5) and its corresponding palladium precatalyst (1), is described. The reactions allow the cross-coupling of both potassium and cesium hydroxides with (hetero)aryl ha...
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Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2015-06-19T14:50:28Z.
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Subjects: | |
Online Access: | Get fulltext |