New Advances in Sc-Catalyzed Diazoalkane Homologation Reactions: The Total Synthesis of pre-achyrofuran and the Desymmetrization of Bicyclic β-Dicarbonyls
Thesis advisor: Jason Kingsbury === Recent findings have led to the discovery that the Sc-catalyzed addition of substituted diazoalkanes to aldehydes elegantly affords a net carbon insertion into the C-H bond, delivering the requisite ketone in one simple step with no need for a readjustment in oxid...
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| Format: | Others |
| Language: | English |
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Boston College
2010
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| Online Access: | http://hdl.handle.net/2345/1202 |