Crystal Structure of a Rigid Ferrocence-based Macrocycle from High-Resolution X-ray Powder Diffraction.

No === A macrocycle, 6, has been synthesized in high yield from 2,5-di(pyrazol-1-yl)hydroquinone and 1,1`-fc[B(Me)NMe2]2 {fc = Fe(C5H4)2}. The molecule incorporates two redox-active 1,1`-ferrocenylene units in its backbone and contains four chiral boron centers, each of them possessing the same conf...

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Bibliographic Details
Main Authors: Dinnebier, R.E., Ding, L., Ma, K., Neumann, M.A., Tanpipat, N., Leusen, Frank J.J., Stephens, P.W., Wagner, M.
Language:en
Published: 2009
Subjects:
Online Access:http://hdl.handle.net/10454/3984