A Combined Experimental and Computational Study of Ligand Effects on C-H Bond Activation by Palladium and Platinum Complexes
<p>Abnormally large kinetic hydrogen/deuterium isotope effects (KIEs, ~ 20) are measured for the protonolysis of several dimethylpalladium(II) complexes with various bidentate ligands by trifluoroethanol (TFE) at room temperature. Analyses of semiclassical KIE theory suggest that the occurrenc...
Internet
https://thesis.library.caltech.edu/1255/1/bolin_thesis_final.pdfLin, Bo-Lin (2009) A Combined Experimental and Computational Study of Ligand Effects on C-H Bond Activation by Palladium and Platinum Complexes. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/PD2Z-QZ56. https://resolver.caltech.edu/CaltechETD:etd-04022009-144521 <https://resolver.caltech.edu/CaltechETD:etd-04022009-144521>