Deviations from chain ideality : are they detectable in simulations and neutron scattering of polyisobutylene ?
The Flory ideality hypothesis states that flexible polymer chains in a melt assume the shape of three-dimensional random walks leading to so called Gaussian coils. The basis of this hypothesis is that any local conformational information decays exponentially along the chain backbone and thus has no...
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Language: | English |
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Université de Strasbourg
2013
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Online Access: | http://tel.archives-ouvertes.fr/tel-01064158 http://tel.archives-ouvertes.fr/docs/01/06/41/58/PDF/zabel_julia_2013_ED182.pdf |