Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents

Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents

Recently, we have described the synthesis of chiral metal–organic frameworks iPr-ChirUMCM-1 and Bn-ChirUMCM-1 and their use in enantioselective separation. Here, we demonstrate for the first time the use of a chiral solvating agent (1-phenyl-2,2,2-trifluoroethanol, TFPE) for chiral recognition in iP...

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Bibliographic Details
Main Authors: Hoffmann, Herbert C., Paasch, Silvia, Müller, Philipp, Senkovska, Irena, Padmanaban, Mohan, Glorius, Frank, Kaskel, Stefan, Brunner, Eike
Other Authors: Royal Society of Chemistry,
Format: Article
Language:English
Published: Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden 2014
Subjects:
Metall-organische Gerüste
MOF
MRT
Magnetresonanztomographie
Polymere
Raumtemperatur
Spin Crossover
poröse Festkörper
Adsorption
NMR-Spektroskopie
Metal-organic framework
resonance spectroscopy
magnetic resonance imaging
coordination polymer
room temperature
spin crossover
porous solids
configuration
adsorption
simulations
assignment
reagents
ddc:540
rvk: VA 1120
Online Access:http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-138884
http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-138884
http://www.qucosa.de/fileadmin/data/qucosa/documents/13888/10.1039c2cc35366k.pdf

Internet

http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-138884
http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-138884
http://www.qucosa.de/fileadmin/data/qucosa/documents/13888/10.1039c2cc35366k.pdf

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