Palladium(II)-catalysed total synthesis of naturally occurring pyrano[3,2-a]carbazole and pyrano[2,3-b]carbazole alkaloids

Seven naturally occurring pyranocarbazole alkaloids (pyrayafoline A–E, O-methylmurrayamine A and O-methylmahanine) have been obtained by total synthesis using a palladium(II)-catalysed oxidative cyclisation of a diarylamine to an orthogonally diprotected 2,7-dihydroxycarbazole as key step.

Bibliographic Details
Main Authors: Hesse, Ronny, Jäger, Anne, Schmidt, Arndt W., Knölker, Hans-Joachim
Other Authors: Royal Society of Chemistry,
Format: Article
Language:English
Published: Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden 2014
Subjects:
Online Access:http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-149135
http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-149135
http://www.qucosa.de/fileadmin/data/qucosa/documents/14913/c4ob00367e_publishedVersion.pdf