Viridiofungins and xeniolide F: target oriented synthesis using different rearrangement reactions of a common substrate class

Viridiofungins and xeniolide F: target oriented synthesis using different rearrangement reactions of a common substrate class

The present dissertation covers the total synthesis of viridiofungin triesters and studies toward the total synthesis of xeniolide F. In both cases, sigmatropic rearrangements of α-allyloxy substituted α,β-unsaturated esters are employed: for the viridiofungin ester synthesis a [2,3]-Wittig rearrang...

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Bibliographic Details
Main Author: Pollex, Annett
Other Authors: Technische Universität Dresden, Chemie und Lebensmittelchemie
Format: Doctoral Thesis
Language:English
Published: Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden 2006
Subjects:
rearrangements
[2
3]-Wittig rearrangement
Claisen rearrangement
diterpene
alkyl citrate
allyl vinyl ether
sigmatrope Umlagerungen
3]-Wittig-Umlagerung
Claisen-Umlagerung
Diterpene
Alkylcitrate
Allylvinylether
ddc:540
rvk:VK 5507
Sigmatrope Umlagerung
Wittig-Umlagerung
Citrate
Allylverbindungen
Online Access:http://nbn-resolving.de/urn:nbn:de:swb:14-1160474365794-44380
http://nbn-resolving.de/urn:nbn:de:swb:14-1160474365794-44380
http://www.qucosa.de/fileadmin/data/qucosa/documents/1850/1160474365794-4438.pdf

Internet

http://nbn-resolving.de/urn:nbn:de:swb:14-1160474365794-44380
http://nbn-resolving.de/urn:nbn:de:swb:14-1160474365794-44380
http://www.qucosa.de/fileadmin/data/qucosa/documents/1850/1160474365794-4438.pdf

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