Synthesis and Characterization of Five New Tetrakis(N-phenylacetamidato) Dirhodium(II) Amine Complexes and One Molybdenum Cofactor Described Crystallographically

Synthesis and Characterization of Five New Tetrakis(N-phenylacetamidato) Dirhodium(II) Amine Complexes and One Molybdenum Cofactor Described Crystallographically

Six new crystal structures were determined using a Rigaku Mercurcy 375/MCCD(XtaLab mini) diffractometer. The structure of a molybdenum cofactor was solved resulting in an R1 (R1 = Σ ||Fo| - |Fc|| / Σ |Fo|) of 3.61% despite the presence of a disordered DMSO molecule. New Tetrakis(N-phenylacetamidato)...

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Bibliographic Details
Main Author: Harris, Cragin K
Format: Others
Language:English
Published: Digital Commons @ East Tennessee State University 2015
Subjects:
X-ray Crystallography
Dirhodium(II)
Phenylacetamide
Molybdenum
Cofactor
Catalyst
Imidazole
4
4-Bipyridine
1
5-Naphthyridine
Inorganic Chemistry
Online Access:https://dc.etsu.edu/etd/2525
https://dc.etsu.edu/cgi/viewcontent.cgi?article=3848&context=etd

Internet

https://dc.etsu.edu/etd/2525
https://dc.etsu.edu/cgi/viewcontent.cgi?article=3848&context=etd

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