Influence Of The Bite Angles Of Chelating Diphosphine Ligands In The Chemistry Of Ruthenium Hydride And Dihydrogen Complexes

The bite angle of a diphosphine ligand plays an important role in determining the reactivity of a transition metal complex. The coordinated dihydrogen on a transition metal center can be activated toward homolysis or heterolysis depending upon the nature of the metal center and the ancillary ligand...

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Bibliographic Details
Main Author: Sivakumar, V
Other Authors: Jagirdar, B R
Language:en_US
Published: Indian Institute of Science 2007
Subjects:
Online Access:http://hdl.handle.net/2005/293