Dinitrogen complexes of titanium and vanadium stabilized by phosphine ligands
The goal of the work presented in this thesis is to investigate the preparation of dinitrogen complexes of titanium and vanadium from phosphine-based starting materials. The reactions of TiCl₄, TiCl₃(THF)₃, or VCl₂(TMEDA)₂ with LiN(SiMe₂CH₂PR₂)₂ (R = isopropyl or methyl) yielded the new phosphine co...
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| Language: | English |
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2008
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| Online Access: | http://hdl.handle.net/2429/1315 |