New bis(amidate) Titanium-bis(amido) complexes as hydroamination precatalysts : synthetic and mechanistic investigations
This thesis focuses on the exploration of a new titanium complex for the hydroamination of alkynes/alkenes. A new pentafluoro amide proligand, [HNC4H9CO( CeF5)] 5, and two related bis(amidate)titanium-bis(amido) complexes (8 and 9) were designed, prepared and fully characterized by multinuclear N...
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| Language: | English |
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2009
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| Online Access: | http://hdl.handle.net/2429/15034 |