Paramagnetic organometallic complexes of chromium, iron and cobalt
The chemistry of the amidodiphosphine ligand ⁻N(SiMe₂CH₂PPh₂)₂ with chromium, iron and cobalt metal centres in the +2 and +3 oxidation states is explored. Metal-chloride complexes MCl[N(SiMe₂CH₂PPh₂)₂] are high-spin and tetrahedral for iron(II) and cobalt(II) and dinuclear with bridging chlorides...
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| Language: | English |
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2009
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| Online Access: | http://hdl.handle.net/2429/6736 |