Pyridine diamide complexes of early transition metals

Titanium complexes bearing a pyridine-diamide ligand [2,6-(RNCH2)2NC5H3]2' (R = 2,6-diisopropylphenyl (BDPP); R = 2,6-dimethylphenyl (BDMP)) have been synthesized. The dichloride complexes [2,6-(RNCH2)2NC5H3]TiCl2 are prepared in high yield from {2,6- [(Me3Si)RNCH2J2NC5H3} and TiCl4 via the...

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Bibliographic Details
Main Author: Guérin, Frédéric
Language:English
Published: 2009
Online Access:http://hdl.handle.net/2429/8411