L-ribulose-5-phosphate 4-epimerase: epimerisation through carbon-carbon bond cleavage

L-Ribulose-5-phosphate 4-epimerase, a bacterial enzyme which catalyses the final step in L-arabinose metabolism, interconverts L-ribulose-5-phosphate and D-xylulose-5-phosphate independently of NAD+. The labile stereocentre does not bear an acidic proton; therefore, a simple deprotonation-reproto...

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Bibliographic Details
Main Author: Johnson, Anne Elizabeth
Language:English
Published: 2009
Online Access:http://hdl.handle.net/2429/8686