Delayed-onset Polymer Cross-linking using Functional Nitroxyls

Delayed-onset Polymer Cross-linking using Functional Nitroxyls

New polymer cure chemistry is described, wherein the onset of free radical cross-linking is delayed without compromising cure yields. The addition of an acrylate-functionalized nitroxyl, 4-acryloyloxy-2,2,6,6-tetramethylpiperidine-N-oxyl (AOTEMPO), to a peroxide-cure formulation quenches free radica...

Full description

Bibliographic Details
Main Author: Hyslop, David
Other Authors: Queen's University (Kingston, Ont.). Theses (Queen's University (Kingston, Ont.))
Language:en
en
Published: 2012
Subjects:
tempo
crosslink
polyethylene
cross-link
cure
delayed action
dicumyl peroxide
radical
nitroxyl
scorch
Online Access:http://hdl.handle.net/1974/7275

Internet

http://hdl.handle.net/1974/7275

Similar Items