ENANTIOSPECIFIC, REGIOSELECTIVE SUZUKI-MIYAURA CROSS-COUPLINGS OF SECONDARY, ALLYLIC BORONIC ESTERS
The stereochemical course of the Pd–catalyzed Suzuki-Miyaura cross-coupling of α-substituted, enantioenriched allylic boronic esters with phenyl iodide has been examined. The secondary boronic esters were prepared in both racemic and enantioenriched forms via borylationof a lithiated carbenoid wit...
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Language: | en en |
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2013
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Online Access: | http://hdl.handle.net/1974/8463 |