Synthesis and Characterization of Iron-Amide and Iron-Imide-Sulfide Clusters
The iron-molybdenum cofactor (FeMo cofactor) is the catalytic center of nitrogen fixation in molybdenum-dependent nitrognease enzymes. The resting state cofactor is a complex [MoFe7S9X] cluster, in which the central ligand X is a central hexacoordinated monoatomic light atom (2p), and the exact iden...
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| Language: | en |
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2011
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| Online Access: | http://hdl.handle.net/10012/6189 |